Not sure why your LT keep adding fuel unless youa re seeing more ethanol or just better air/temps. All things being equal, your LT should get close to "0" by themselves. Your ST and LT trims adjustments are basically tweaking fuel delivery to keep your afr at stoich.
If you change B3601 to 14.16, 14.16 becomes your stoich. EFILive will then make changes to your OLCF table and your PE tables reflecting changes to B3601.
Much is dependent on what your currently have B3601 currently set at using your 91 fuel. If your B3601 is set to say, 14.63 and your change B3601 to 14.16, your PE table will change as well. I will assume your current B3601 is 14.63 and your PE table is flatlined at 12.3. If you change B3601 to 14.16, your PE table will be revised to approx 11.7:1 from 12.3:1. 11.7:1 is rich for even e10.
Try it. Create a dummy tune file of a current file. Change B3601 to 14.16. Save it. Open file back up and look at look at PE table. You will have new values.
My suggestion, find out what ethanol content is in your area. I bought a test kit used by airplane owners. I get mine from EAA in Oshkosh, WI. In SE WI, our E10 is really E5 for the summer blend.
Not sure about all WB's as far as readings. I believe Innovative LC1/etc c an be programmed to reflect revised stoich.
As far as E85, your could adjust B3601 to reflect stoich for E85 9.85. You would be in the ballpark. Question would be, are injectors and fuel system able to meet demand?